PittsburghV1, France, Analysis, bibRecord, 000520

The Parent Borylene: Betwixt and Between

Identifieur interne : 000520 ( France/Analysis ); précédent : 000519; suivant : 000521

The Parent Borylene: Betwixt and Between

Auteurs : Dennis P. Curran [États-Unis] ; Anne Boussonnière [États-Unis] ; Steven J. Geib [États-Unis] ; Emmanuel Lacôte [France]

Source :

Angewandte Chemie International Edition [ 1433-7851 ] ; 2012-02-13.

RBID : ISTEX:66205BD557437E2360AEE745B6E705928B06F492

English descriptors

KwdEn :
- Aliphatic, Aliphatic products, Alkyl, Alkyl halides, Angew, Angewandte, Anion, Boriranes, Boryl, Boryl dichlorides, Borylene, Braunschweig, Chem, Cleaner crude product, Crystal structures, Curran, Electron transfer, Equiv, Fensterbank, Flash chromatography, Geib, Gmbh, Halide, Insertion, Insertion product, Insertion products, Kgaa, Ldbb, Makhlouf brahmi, Malacria, Naphthalene, Naphthalenide, Sodium naphthalenide, Solovyev, Triplet, Verlag, Verlag gmbh, Weinheim, Weinheim angew.
Teeft :
- Aliphatic, Aliphatic products, Alkyl, Alkyl halides, Angew, Angewandte, Anion, Boriranes, Boryl, Boryl dichlorides, Borylene, Braunschweig, Chem, Cleaner crude product, Crystal structures, Curran, Electron transfer, Equiv, Fensterbank, Flash chromatography, Geib, Gmbh, Halide, Insertion, Insertion product, Insertion products, Kgaa, Ldbb, Makhlouf brahmi, Malacria, Naphthalene, Naphthalenide, Sodium naphthalenide, Solovyev, Triplet, Verlag, Verlag gmbh, Weinheim, Weinheim angew.

Abstract

Still elusive: The reduction of dimethylimidazol‐2‐ylidene dichloroborane by sodium naphthalenide has been suggested to provide a borylene that cycloadds to naphthalene to make a borirane. Evidence has been provided that this borirane instead arises from coupling of a boryl radical and sodium naphthalenide. In contrast, reduction of 1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene dichloroborane and the related dimesityl derivative provide novel CH insertion products that may have arisen from a borylene.

Url:

https://api.istex.fr/document/66205BD557437E2360AEE745B6E705928B06F492/fulltext/pdf

DOI: 10.1002/anie.201107238

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 001747
to stream Istex, to step Curation: 001747
to stream Istex, to step Checkpoint: 001268
to stream Main, to step Merge: 007D99
to stream Main, to step Curation: 007922
to stream Main, to step Exploration: 007922
to stream France, to step Extraction: 000520

Links to Exploration step

ISTEX:66205BD557437E2360AEE745B6E705928B06F492

Le document en format XML

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<author><name sortKey="Boussonniere, Anne" sort="Boussonniere, Anne" uniqKey="Boussonniere A" first="Anne" last="Boussonnière">Anne Boussonnière</name>
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<front><div type="abstract">Still elusive: The reduction of dimethylimidazol‐2‐ylidene dichloroborane by sodium naphthalenide has been suggested to provide a borylene that cycloadds to naphthalene to make a borirane. Evidence has been provided that this borirane instead arises from coupling of a boryl radical and sodium naphthalenide. In contrast, reduction of 1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene dichloroborane and the related dimesityl derivative provide novel CH insertion products that may have arisen from a borylene.</div>
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   |wiki=    Wicri/Amérique
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   |texte=   The Parent Borylene: Betwixt and Between
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The Parent Borylene: Betwixt and Between

The Parent Borylene: Betwixt and Between

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri